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There's a post on this by the wonderful Jim Leichliter: http://captivatedev.com/2011/05/01/how-to-jump-to-a-specific-slide-in- a-separate-course/
But you might want to take a look at an exchange in the comments:
I'd prefer the project to be a swf, is it possible to open the file on a specific slide if it's published as an exe?
Unfortunately not. The JavaScript API only applies to web based content. If you need to run the project locally, I'd recommend using Adobe AIR. Inside of AIR, you can run JavaScript.
